White balance is a tricky thing to define. First and foremost, 5600K is the color temperature as the light leaves the tube. There is then the color shift introduced by the diffusion dome, which is about 300K, leaving the color temperature at about 5300K. Then the modifiers can then add a shift, silver may add a little in one direction (maybe 100K or so), and white fabrics will drop temperature about 200K. This is if you have a white fabric that has not been treated with optical brightners, that "make whites whiter". These can shift the color up by 1000K to the blue.
Then you have factors within the camera. Each camera will record color a little different, and each lens can have a different shift (I have seen this even with the same model lens). If there are any filters on the lens, that can shift color as well.
I have no test data on the neutrality of an Expos Disc, but I will assume it is fine. However, you are measuring the light from the source, but not necessarily the light falling on your subject.
If there is a large window that can also contribute light and color, and may or may not be accounted for by the Expo Disc. Large surfaces of color (like walls, ceilings, carpet) can also affect the color hitting the subject.
Then you have different software programs that define color differently. I found a significant shift in defined temperature between Adobe Camera Raw and iPhoto, and neither of these agree with the color meter used. I forget the actual numbers, but the spread was pretty close to 800-1000K.
Ultimately, it matters little what the actual color temperature is (as long as each light is close to the others, which is the importance of the COLOR mode) or how the software defines it, as long as it is neutralized by the Expo Disc. And really, if all color temperature was straightforward and predictable, the need for the Expo Disc would not be present.
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