1. Poolside optical triggers won't work well in your situation, as the water->air boundary will reflect over 90% of the trigger flash's energy back into the pool, and the remaining few % would be easily overpowered by ambient light.
2. Your speedlites, if placed poolside would have to be placed and aimed rather particularly, taking into account that air-> water boundary will change the direction of light and can also reflect much of the energy away if you are not careful.
3. RF
can travel underwater a limited distance if it is designed accordingly. My air-integrated cordless diving computer is using that tech (range of a few feet), and RF based underwater voice comm (range around 100 yards) originally designed for the U.S. Navy has been trickling into commercial products the last few years (though it's still expensive). I know of no off-the-shelf underwater camera triggers though.
In your situation I can think of 2 approaches:
A). Go under. Get your speedlites with digital-capable optical triggers into some Ewa-Marine flexible housings (intended for compact cams, relatively inexpensive). The whole setup should work in the pool about as well as in the air.
B). Go wired. A soldering iron and a silicone caulk are your friends.
-- Alex Karasev
principal photographer
Karasev Studio
http://karasevstudio.com/