The easy way would be with a flash meter. However, you can look here for guide numbers and measured apertures at full power for various modifiers:
http://www.paulcbuff.com/output.php These measurements are at ISO100.
Guide numbers will help you find an aperture based on distance, or distance based on an aperture.
So with a guide number of 110, divide that by 10 (feet) and you get (f/)11.
If you use a softbox, that is a GN of 102. At 5ft, that is f16 and 7/10 (a.k.a f/20). If your sunset meters at f/8 (from your camera's meter), then you will dial the light down 2 and 7/10 of a stop to match the f/8.
This is slightly simplified, but it will get you in the ballpark.