.33 is 1/3 and .66 is 2/3. So if you have f/11' 3, you have 1/3 stop more than f/11. If your camera is set to 1/3 stop increments, you would set one click above f/11. If you meter f/11'6, you essentially have 2/3 more than f/11. Here you would click twice above f/11. You amy also see a difference between your two meters, depending on whether or not the Sekonic is set to 1/3, 1/2, or 1/10 stop increments.
Also, you may still see some overexposure in your camera as some (if not all) cameras fudge the ISO value to cause a little over exposure. Slight overexposure (or "exposing to the right") is an often used technique to help limit noise in an image.
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